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Asymmetric H–D exchange reactions of fluorinated aromatic ketones
- TCHLab
- Mar 30, 2012
- 1 min read
Updated: Aug 14, 2024
Yujun Zhao, Xiaozhi Lim, Yuanhang Pan, Lili Zong, Wei Feng, Choon-Hong Tan and Kuo-Wei Huang
Chemical Communications, 2012, 48, 5479 – 5481
Abstract: Chiral bicyclic guanidine catalyzes the asymmetric H–D exchange reactions. Up to 30% ee was achieved. DFT calculations were employed to elucidate and explain the origin of the reaction's stereoselectivity.
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