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Air Oxidation of HS– Catalyzed by An Mixed-Valence Diruthenium Complex,

an Near-IR Probe for HS– Detection


Yi-Ling Quek, Choon-Hong Tan, Jinsong Bian, Dejian Huang

Inorganic Chemistry, 2011, 50, 7379–7381


Abstract: The strongly near-IR-active mixed-valence diruthenium complex [Ru2TIEDCl4]Cl, where TIED = tetraiminoethylenedimacrocycle, was found to be a highly active catalyst for air oxidation of HS– forming polysulfide species and H2O2. The reaction provides a convenient method for the detection of the HS– generation rate of a H2S donor of medical importance.


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